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Extra info for Encyclopedia of Polymer Research (2 Volume Set)

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Jones ISBN: 978-1-61761-926-7 © 2011 Nova Science Publishers, Inc. Chapter 1 RESEARCH AND REVIEW AND STUDIES INDUCED SELF-ASSEMBLY OF DIBLOCK COPOLYMERS Eri Yoshida Department of Materials Science, Toyohashi University of Technology, Hibarigaoka, Tempaku-cho, Toyohashi, Aichi 441-8580, Japan 1. INDUCED SELF-ASSEMBLY BY ELECTRON TRANSFER The molecular self-assembly is induced by variation in the surroundings, such as temperature [1-4], pressure [5-9], pH [10-14], salt formation [13-18], and noncovalent bond cross-linking [1921].

Macromolecules, 35, 6121. , Jiang M (1999). Polymer, 40, 5449. , Chen P (1985). Tetrahedron Lett, 26, 4201. , Armes SP (1997). Chem Commun, 1035. [28] Marquardt DW (1963). J Soc Indust Appl Math, 11, 431. , Webber SE (1996). Macromolecules, 29, 6071. , Triolo R (1996). Science, 274, 2049. , Ogawara M (1985). J Org Chem, 50,1332. , Nostrum, C. , Hennink, W. E. (2001). Macromolecules, 34, 7589. , Dais P (1977). Chem Commun, 10, 345. , Flores L (1988). Heterocycles, 27, 509. [35] Rozantsev, E. G. & Golubev, V.

Oxidation-Induced Micellization Oxidation-induced micellization of a diblock copolymer was determined for a diblock copolymer containing 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) on the side chains [30]. TEMPO is a stable nitroxyl radical known as a spin trapping reagent [31], a spin label reagent [32], and a mediator for living radical polymerization [33, 34]. TEMPO forms a redox system in which the radical is converted into the oxoaminium cation (OA) by one-electron oxidation and is converted into the aminoxy anion (AA) by one-electron reduction [35] (Figure 1-1-1).

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